The effectiveness of activated carbon in amine desulfurization is mainly affected by the following factors:
I. Activated Carbon's Intrinsic Characteristics
Specific Surface Area: A larger specific surface area provides more adsorption sites, but this needs to be matched to the size of the pollutant molecules.
Pore Size Distribution: Micropores (<2nm) are suitable for adsorbing small gas molecules.
Mesopores (2-50nm) are suitable for larger organic molecules.
Macropores (>50nm) are suitable for colloidal substances.
Particle Size and Shape: Powdered form has high adsorption efficiency, while columnar form has high mechanical strength.
Surface Chemical Properties: Oxygen-containing functional groups enhance the adsorption of polar molecules.
Ash and Impurities: High ash content reduces the effective adsorption area.
II. External Conditions
Temperature: Low temperatures favor adsorption (exothermic reaction).
High temperatures may trigger desorption.
A balance between temperature and efficiency is necessary in actual operation.
pH Value: Acidic environments (pH 3-5) provide good adsorption.
Alkaline environments may weaken adsorption. Contaminant Concentration: Excessive concentration may lead to adsorption saturation.
Contact Time: Too short a time results in insufficient adsorption, while too long a time may trigger re-adsorption.
III. Operating Parameters
Solvent Circulation Rate: Insufficient flow rate affects absorption efficiency, while excessive flow rate increases power consumption.
Pressure: High pressure promotes adsorption, but excessive pressure may cause liquefaction of heavy components.
IV. Other Factors
Oxygen and Moisture: These can promote chemisorption, but water vapor concentration affects sulfuric acid formation.
Activated Carbon Impregnation: Metal salt impregnation can improve adsorption capacity.

